Effectiveness of high-field MQMAS
NM070008E
In solid-state NMR for inorganic materials where quadrupolar interactions dominate linewidths and lineshapes, high magnetic fields dramatically enhance resolution and sensitivity since the second-order quadrupolar broadenings are inversely proportional to the magnetic fields.
High magnetic fields also enhance resolution and sensitivity of MQMAS spectra, and so they are preferable for MQMAS measurements.
Sample: RbNO3
Spectrometer: JNM-ECA400, JNM-ECA930
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