Close Btn

Select Your Regional site

Close

Our paper has been published in "Solid State Nuclear Magnetic Resonance"

Release Date: 2022/01/20

Our paper has been published in "Solid State Nuclear Magnetic Resonance". It is a collaborative work by RIKEN-JEOL Collaboration Center, TIFR Hyderabad and JEOL RESONANCE Inc.
We have developed a novel method to probe local 1H-1H proximities through DQ/SQ correlations in rigid solid. The method is called MIxed Selective Excitation/Recoupling And Broadband recoupLing Experiment (MISERABLE).
Although 2D DQ/SQ spectra have been widely used to observe proximities, heavily overlapped 1H resonances often pose difficulty to resolve correlations. In MISERABLE approach, a well separated 1H peak is selectively excited then selectively transferred to neighboring 1Hs. This MISE scheme allows selective polarization of a particular 1H regardless to spectral overlaps. Finally, DQ/SQ correlation is observed to probe the local proximities of the selected 1H nucleus. We believe the method is useful for structural analysis of small to middle sized molecules.

Link

Close
Notice

Are you a medical professional or personnel engaged in medical care?

Yes

No

Please be reminded that these pages are not intended to provide the general public with information about the products.